The discovery of heusler alloys dates back to 1903 when heusler reported that the addition of sp elements al, in, sn, sb or bi turn cumn alloy into a ferromagnetic material even though the alloy contains none of the ferromagnetic elements 37. There are so many possible sets of x, y,andz figure 2. Wo2012087931a2 halfheusler alloys with enhanced figure of. Nov 14, 2014 the electronic structure and magnetism of the heusler alloys fe2crx x p, as, sb, bi have been investigated by firstprinciples calculations based on density functional theory. Heusler compounds are a remarkable class of materials with more than. Co mnsi heusler alloy thin films connecting repositories. Heusler alloys ha are a class of materials which may be metals, semiconductors or semimetals, most of them being ferromagnets. The calculations show that all fe2crx alloys are halfmetals with a magnetic moment of 3. New heusler compounds in nimnin and nimnsn alloys nature. Heusler alloy definition of heusler alloy by merriamwebster.
Heusler alloy, any of the first magnetic alloys composed of metals that, in their pure state, are not magnetic. In the recent decade, the family of heusler compounds has attracted. The hope of breakthrough for the data writing was provided by the prediction. Magnetic, structural, and transport properties of the heusler alloys co 2 mnsi and nimnsb. Halfmetallic heusler alloys are attracting considerable attention because of their unique halfmetallic band structures, which exhibit high spin polarization and yield huge magnetoresistance ratios. Pdf mechanical properties of heusler alloys researchgate. The do 3 and a2type disorders do not affect the halfmetallicity in mn 2 cosi the b2type disorder solely destroys halfmetallicity in mn 2 cosi the a2type disorder most probable to occur out of all three types the total spin magnetic moment strongly depends on the disorder concentrations. Half heusler alloys as promising thermoelectric materials by alexander a. Abstract page 2 abstract heusler alloys are one of the leading candidate material classes for achieving high spin. The method includes combining and arc melting constituent elements of the thermoelectric material to form a liquid alloy of the thermoelectric material and casting the liquid alloy of the thermoelectric material to form a solid casting of the thermoelectric material. After years of experimentation, it was found that a typical heusler compound has a face centered cubic fcc structure which comprises, essentially, of an ordered. These heusler alloys present an interesting class of. Introduction heusler alloys are known for more than 100 years.
This database provides information on three families of heusler alloys, full heuslers a 2 bc, half heuslers abc and inverse heuslers abac. He found that one was facecentred cubic, while the other was a mixture of facecentred and bodycentred cubic structures. Exchange interactions and temperature dependence of. The database, developed by william butlers group at the university of alabama and prof. A heusler alloy is an intermetallic compound ordered alloy described as x 2 yz with an l2 1 structure.
Heusler alloys consist of approximately two parts of copper, one of manganese, and one of tin. Download it once and read it on your kindle device, pc, phones or tablets. Some alloys are listed under more than one element, since the composition of the alloy may vary such that one element is present in a higher concentration than the others. Its magnetism varies considerably with heat treatment and composition. Some new applications of ha in spintronics and micro. The calculations show that all fe 2 crx alloys are halfmetals with a magnetic moment of 3. Direct observation of halfmetallicity in the heusler.
Disorder dependent halfmetallicity in mn 2 cosi inverse. Among the fe 2based heusler alloys, the fe 2crz z is the main group. Heusler alloys are unusual in that they exhibit ferromagnetic ordering without necessarily containing any pure ferromagnetic elements. The tin may be replaced by aluminum, arsenic, antimony, bismuth, or boron. Heusler alloy database electrical and computer engineering. The following investigation of the properties of these alloys. This book gives an overview of the physics of heusler compounds ranging. Heusler article about heusler by the free dictionary. The crystal structure of the heusler alloys proceedings. It is called a full heusler alloy in a narrow sense, whereas xyz with a c1 b structure is called a half heusler alloy. Introductionthe heusler alloys, so named in honor of their discoverer, are composed of copper, manganese and aluminum, and are remarkable for the fact that, in certain proportions, they are ferromagnetic, although the component metals are not ferromagnetic. They are named after friedrich heusler, a german mining engineer and chemist, who discovered in 1903 cumnal to be ferromagnetic. Optimisation of heusler alloy thin films for spintronic devices james sagar submitted for the degree of doctor of philosophy the university of york department of physics july 20. Heusler alloys comprise an extensive family with diverse physical properties1.
Heusler alloys x2yz are wellestablished intermetallic compound materials in various fields because their function can be precisely adjusted by elemental substitution e. Structural properties of magnetic heusler alloys iopscience. Development of antiferromagnetic heusler alloys for the. An unusual charge signal was observed with a sign change at low temperature, which can be manipulated by film thickness and ordering structure. A small lack of compensation produces giant exchange bias and large coercivity.
Full text of magnetic properties of heusler alloys see other formats library university of california. Any of a group of ferromagnetic nonferrous alloys typically composed of 1825% manganese, 1025% aluminum, and the balance copper explanation of heusler heusler article about heusler. Pdf soft phonon modes in ni2mnga and ni2mnal heusler alloys. Computational investigation of heusler alloys for spintronic. Heusler alloys consisting of elements with moderate magnetic moments require perfectly or partially ordered crystalline structures to exhibit af behaviour. Heusler compounds are intermetallics with intriguing magnetic properties. The heusler alloys, so named in honor of their discoverer, are composed of copper, manganese and aluminum, and are re. Typically, x and y are transition metals in groups 38 and 812, respectively, and z is in group 15.
Here, we report on the spincharge conversion effect in the prototypical heusler. Heusler alloy definition is a magnetic alloy composed of the nonmagnetic metals copper, manganese, and tin approximately in the proportions cu2mnsn. Applied physics copyright 2019 spincharge conversion. Here, we report on the spincharge conversion effect in the prototypical heusler alloy nimnsb.
The heusler alloys have been repeatedly investigated by means of xrays. Us20120326097a1 halfheusler alloys with enhanced figure of. It contained two parts copper, one part manganese, and one part tin, that is cu 2 mnsn, and has the following properties. Creep of an alloy based on the intermetallic compound fe2alco was studied by compressive creep tests in the temperature range from 873 to 1073 k.
Chapter 2 half heusler alloys as thermoelectric materials. The stress exponent n and the activation energy of creep q were determined using the multivariable regression of the creeprate data and their description by means of sinh equation garofalo equation. Poon1,a 1 department of physics, university of virginia, charlottesville, virginia 229044714 2 department of physics and astronomy, clemson university, clemson, south carolina 296340978. Electronic structure, magnetic and optical properties of heusler alloy. This feature predicts a discovery of new catalysts, and enables them to substitute each other e. The disordered defects at all atomic sites induce a. Since both hamiltonians differ only by the potentials. The term derives from the name of german mining engineer and chemist friedrich heusler, who studied such a compound in 1903. By using elements with large magnetic moments, even a fully disordered structure is found to show either af or ferrimagnetic fi behaviour. Magnetic properties of heusler alloys classic reprint stephenson, edward beattie on. Novel halfmetallic and spingapless heusler compounds yunlong jin, ph. Typically, x and y are transition metals in groups 3.
Pdf in the recent decade, the family of heusler compounds has. Half heusler alloys for efficient thermoelectric power conversion l. Herein, the use of scanning transmission electron microscopy to visualize atomic defects directly is described and disordered atomic. These heusler alloys present an interesting class of ferromagnetic materials for spintronic applications since they are predicted to be spin gapless semiconductors and have halfmetallic properties with 100 % spin polarization at the fermi level. Since there is no simple univocal experiment to test for half.
Frontier institute of science and technology and state key laboratory for mechanical. The heusler alloys are categorized into two distinct groups by their crystalline structures. B at their respective equilibrium lattice constants, which is in good agreement with the slaterpauling rule. Heusler alloys chris palmstrom research group uc santa. Magnetic, structural, and transport properties of the heusler. Magnetic properties of heusler alloys classic reprint. These alloys were interesting because some of them were ferromagnetic even though their constituent atoms were nonferromagnetic as elements. They are named after friedrich heusler, a german mining engineer and chemist, who discovered in 1903 cumnal to be ferromagnetic, although the alloy consists of nonferromagnetic elements.
This is an alphabetical list of alloys grouped according to base metal. Basics and prospective of magnetic heusler compounds. Young, using molybdenum radiation examined alloys of two different compositions. Since the prediction of the half heusler halfmetal nimnsb with 100% spin polarization2,many studies have been devoted to searching for and verifying heuslers with halfmetallicity. Hilli suggests,that there is a simple explanation of. Sitepreference, electronic, magnetic, and halfmetal. Half heusler alloys for efficient thermoelectric power conversion.
Simple rules for the understanding of heusler compounds. For each of these families, we provide calculations for numerous systems. Heusler alloys are properly described as ternary intermetallic compounds and they can disorder in a variety of ways. Most of the heusler alloys are ferromagnetic, with curie temperatures ranging typically from 200 k to 1100 k. Optimisation of heusler alloy thin films for spintronic.
They are members of the vast family of heusler alloys with the general composition x 2 yz, consisting of three interpenetrating facecentered cubic fcc sublattices space group fm 3. Heusler alloys are one of the leading candidate material classes for achieving high spin polarisation. Halfheusler alloys as promising thermoelectric materials. In 1903 heusler 03 h 1 first reported that mncu bronze can be alloyed with sn, al, as, sb, bi or b to produce ferromagnetic alloys even though none of the constituent elements is itself. Heusler alloys exhibit slaterpauling behavior where the total magnetic.
Professor ctirad uher, chair assistant professor emmanouil kioupakis associate professor lu li. Avik ghoshs group at the university of virginia, provides information on three families of heusler alloys, full heuslers a2bc, half heuslers abc and inverse heuslers abac. Spincharge conversion in nimnsb heusler alloy films. Properties, growth, applications springer series in materials science book 222 kindle edition by felser, claudia, hirohata, atsufumi. The most prominent example is the combination of magnetism and exceptional transport properties in spintronic devices. Abstract heusler alloys, particularly in the family ni2mnz z ga, in, sn and sb and nearby compositions. For each of these families, calculations for numerous systems are. An alloy is a material made by melting one or more metals together with other elements.
Heusler alloy article about heusler alloy by the free. The heusler alloys, so named in honor of their discoverr. However, there are yet to be any reports of this 100% spin polarisation experimentally. Heusler alloys the heusler compounds are an exciting class of intermetallics due to their ability to adopt a wide range of tunable electrical and magnetic properties, including metallicity, half metallic ferromagnetism, superconductivity, and narrow band gap semiconducting behavior with large thermoelectric power factors. Pdf heusler alloys have been a significant topic of research due to their unique. Pdf substituting the main group element in cobaltiron. Received by exchange class university of illinois bulletin vol. Given the energy in 10, it is possible to write down a noninteracting schrodingers.
The discovery of heusler alloys dates back to 1903 when heusler reported that the addition of sp elements al, in, sn, sb or bi turn cumn alloy into a. Pdf in the recent decade, the family of heusler compounds has attracted tremendous. Novel halfmetallic and spingapless heusler compounds. The poscar file can either be constructed using an existing cif file from an online. Heusler alloy is also a typical object for studying the ordered atomic configuration and magnetic coupling for intermetallic compounds2.
Fritz heusler german mining engineer and chemist britannica. Structure and magnetic properties of heusler alloy fe niz. This book gives an overview of the physics of heusler compounds ranging from fundamental properties of these alloys to their applications. The electronic structure and magnetism of the heusler alloys fe 2 crx x p, as, sb, bi have been investigated by firstprinciples calculations based on density functional theory. Some new applications of ha in spintronics and microelectromagnetic actuators require their preparation in the form of thin films. A number of cobased heusler alloys are predicted to be halfmetallic ferromagnets that would theoretically provide 100% spin polarisation at the fermi energy.
Structural properties of magnetic heusler alloys a ayuela, j enkovaara, k ullakko an d r m nieminen laboratory of physics, helsinki university of technology, 02015 espoo, finland materials physics laboratory, helsinki university of technology, 02015 espoo, finland received 16 november 1998 abstract. Thermoelectric materials and methods of making thermoelectric materials having a nanometer mean grain size less than 1 micron. A further analysis of the experimental results reveals a close structural relationship between these two compounds. Further investigations showed that the magnetic properties of these alloys are related to their chemical, l2 1, structure, and to the ordering of the manganese atoms on an f. Besides serving as ferromagnetic electrodes, heusler alloys also have the potential to host spincharge conversion. May 30, 2014 ferromagnetic thin films of heusler compounds are highly relevant for spintronic applications owing to their predicted halfmetallicity, that is, 100% spin polarization at the fermi energy. The first compound in this class of materials was cu 2 mnal, a discovery made in 1903 by friedrich heusler 202 after whom the system is named.
Crystals free fulltext creep of heuslertype alloy fe. The alloys are named after fritz heusler, 19thcentury german mining engineer and chemist. Any of a group of ferromagnetic nonferrous alloys typically composed of 1825% manganese, 1025% aluminum, and the balance copper explanation of heusler. Especially heusler compounds as halfmetallic ferromagnetic and topological insulators are important in condensed matter science due to their potential in magnetism and as materials for energy conversion. Phase transformation and magnetic properties of multicomponent heusler type alloys submitted by mine kalkanci in partial fulfillment of the requirements for the degree of master of science in metallurgical and materials engineering department, middle east technical university by, prof. Design of compensated ferrimagnetic heusler alloys for. Therefore, synthesizing and investigating new systems becomes an attractive subject for investigators working in this field. Any of a group of ferromagnetic nonferrous alloys typically composed of 1825% manganese, 1025% aluminum, and the balance copper explanation of heusler alloy. Exchange interactions and temperature dependence of magnetization in halfmetallic heusler alloys e.
Substituting the main group element in cobaltiron based heusler alloys. Heusler alloys properties, growth, applications claudia felser. Novel halfmetallic and spingapless heusler compounds by. Structure and magnetic properties of heusler alloy fe niz z. The hope of breakthrough for the data writing was provided by the prediction in 1996. An approach to design compensated ferrimagnetic heusler alloys is established. Half heusler alloys for efficient thermoelectric power. Co2mnsi heusler alloy thin films laura jane singh peterhouse cambridge a dissertation submitted for the degree of doctor of philosophy at the university of cambridge. Heusler alloys are named for the german mining engineer and chemist friedrich heusler who investigated cumnal alloys around 1900 1. Page a dissertation submitted in partial fulfillment of the requirements for the degree of doctor of philosophy physics in the university of michigan 2017 doctoral committee.
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